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Determination of the Rate of Tetraethylammonium Ion Transfer across the\nWater/1,2-DCE Interface with Steady-State Voltammetry at a Nano-ITIES
Silver, Barry Richard ; Holub, Karel ; Mareček, Vladimír
The rate of TEA+ ion transfer across the water/1,2-dichloroethane interface has been\nmeasured using steady-state cyclic voltammetry at a capillary with an orifice of nano-sized\ndimension. It was found that the average rate constant for TEA+ transfer from water to oil and\nfrom oil to water is 0.64 cm/s. The results are repeatable using the same capillary. This value\nis similar to that measured previously using electrochemical impedance spectroscopy and\nfluctuation analysis at the micro-interface.

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